Ytterbium (Yb) vs. Aluminium (Al): A Comparison of Their Roles in Glass-Forming Ability of Amorphous Steel

PropertyYtterbium (Yb)Aluminium (Al)
Atomic RadiusLarge atomic radius (222 pm), significantly different from typical metallic elementsSmall atomic radius (143 pm), aids in packing density but complicates alloying
Glass-Forming Ability (GFA)Yb contributes to high GFA when paired with metals like Al, stabilizing amorphous phases due to deep eutectic compositions and minimal crystalline structures.Al’s GFA is lower in isolation but increases significantly in alloys, especially when combined with rare-earth elements or transition metals.
Thermal PropertiesHigh thermal stability in Yb-based alloys, with good glass transition temperatures (Tg) that resist crystallization at lower cooling rates.Al-based amorphous alloys require high cooling rates but can provide high thermal conductivity in composites.
Mechanical PropertiesYb-based alloys demonstrate high elastic limits and yield strengths, making them suitable for high-stress applications.Al-based glasses, while lightweight, tend to have lower mechanical strength compared to Yb-based alloys unless heavily alloyed.
Corrosion ResistanceYtterbium oxides (Yb2O3) form passivating layers that enhance corrosion resistance, particularly in acidic environments.Aluminium oxides (Al2O3) also provide corrosion resistance, but the effectiveness is contingent on alloy composition and environment.
Applications in Amorphous SteelYb contributes to improved toughness and higher glass-forming efficiency in amorphous steels, particularly in high-stress and temperature environments.Al is commonly alloyed to reduce density and increase corrosion resistance, particularly in applications where weight is a critical factor.
Crystallization BehaviorLower crystallization tendency in Yb-rich alloys due to the mismatch in atomic radii and favorable enthalpy of mixing with other metals.Al alloys have a higher tendency to crystallize unless stabilized by specific alloying elements like Zr or lanthanides.

Ytterbium enhances glass-forming ability, mechanical strength, and corrosion resistance in amorphous steel alloys, while aluminium primarily reduces weight and increases corrosion resistance.

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