FCC vs. BCC: Influence on Elastic Properties of Materials, Especially in Metallic Glasses

AspectFCC (Face-Centered Cubic)BCC (Body-Centered Cubic)
Crystal StructureAtoms are arranged in a face-centered cubic structure, with atoms at each corner and the center of each face.Atoms are positioned at the corners of a cube with a single atom at the center.
Atomic Packing Factor (APF)0.74, making FCC more densely packed and allowing better plasticity.0.68, less densely packed than FCC, leading to different mechanical properties.
Slip Systems12 slip systems, enabling greater ductility and better plastic deformation.48 slip systems, but typically fewer are active at low temperatures, resulting in less ductility compared to FCC.
Elastic ModuliHigher Young’s modulus, making FCC structures stiffer and more resistant to elastic deformation.Lower Young’s modulus compared to FCC, resulting in higher elasticity and ductility at low temperatures.
DuctilityFCC materials, like aluminum, copper, and austenitic steels, are generally more ductile and can undergo significant plastic deformation.BCC materials, such as ferritic steels and refractory metals, are less ductile but have higher yield strengths at elevated temperatures.
Thermal PropertiesFCC metals typically have higher thermal conductivity due to their dense atomic arrangement.BCC metals generally exhibit lower thermal conductivity.
Impact on Metallic GlassesFCC-like structures in metallic glasses tend to increase glass-forming ability and improve mechanical resilience.BCC structures, when forming, can contribute to increased brittleness and lower glass-forming ability in metallic glasses.
Stress-Strain BehaviorExhibits higher strain hardening due to the multiple active slip systems, resulting in better workability in processes like rolling.More prone to brittle fracture under certain conditions due to fewer active slip systems.
ApplicationsUsed in ductile metals such as aluminum, copper, and austenitic stainless steels.Preferred for applications requiring strength at high temperatures, such as in ferritic steels and refractory metals.

Improved elastic properties in FCC structures often contribute to their selection for applications requiring a balance between strength and ductility.

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